Jump to main content
Jump to site search

Issue 32, 2017
Previous Article Next Article

Five 1D to 3D Zn(II)/Mn(II)-CPs based on dicarboxyphenyl-terpyridine ligand: stepwise adsorptivity and magnetic properties

Author affiliations

Abstract

Five coordination polymers, {[Zn(dtp)]·H2O} (1), {[Zn(dtp)]·2CH3OH·NMP} (2), {[Mn2(dtp)2(H2O)4]·12(H2O)} (3), {[Mn(Hdtp)(Cl)]} (4) and {[Mn(dtp)(H2O)]·1.5H2O} (5) with different dimensional structures, have been solvothermally synthesized by utilizing the H2dtp ligand (H2dtp = 4′-(3,-5-dicarboxyphenyl)-2,2′:6′,2′′-terpyridine). All complexes are characterized by single-crystal X-ray diffraction, elemental analysis, IR spectra, thermogravimetric analysis (TGA) and powder X-ray diffraction (PXRD). The Zn(II)-based complexes 1 and 2 display a 2D wavy layer structure and a 3D porous framework with a 1D channel, respectively. The three Mn(II)-based complexes 3–5 exhibit two 1D chain and one 2D layer structures, respectively. Complexes 1 and 2 reveal their luminescence properties, whereas complexes 3–5 display an antiferromagnetic exchange. Meanwhile, an unusual stepwise adsorption for CO2 was also observed in 2.

Graphical abstract: Five 1D to 3D Zn(ii)/Mn(ii)-CPs based on dicarboxyphenyl-terpyridine ligand: stepwise adsorptivity and magnetic properties

Back to tab navigation

Supplementary files

Publication details

The article was received on 26 Apr 2017, accepted on 17 Jun 2017 and first published on 27 Jun 2017


Article type: Paper
DOI: 10.1039/C7CE00786H
Citation: CrystEngComm, 2017,19, 4789-4796
  •   Request permissions

    Five 1D to 3D Zn(II)/Mn(II)-CPs based on dicarboxyphenyl-terpyridine ligand: stepwise adsorptivity and magnetic properties

    N. Bai, L. Hou, R. Gao, J. Liang, F. Yang and Y. Wang, CrystEngComm, 2017, 19, 4789
    DOI: 10.1039/C7CE00786H

Search articles by author

Spotlight

Advertisements