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Regiospecific [2+2] photocycloadditions of an unsymmetrical olefin in the solid state based on metal-mediated assemblies

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Abstract

An unsymmetrical olefin in two coordination polymers underwent solid state [2+2] photocycloaddition reactions resulting in quantitative yields. The reactions afforded the head-to-head and head-to-tail photodimer isomers of cyclobutane derivatives with absolute regiospecificities.

Graphical abstract: Regiospecific [2+2] photocycloadditions of an unsymmetrical olefin in the solid state based on metal-mediated assemblies

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Publication details

The article was received on 25 Mar 2017, accepted on 13 Apr 2017 and first published on 13 Apr 2017


Article type: Communication
DOI: 10.1039/C7CE00573C
Citation: CrystEngComm, 2017, Advance Article
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    Regiospecific [2+2] photocycloadditions of an unsymmetrical olefin in the solid state based on metal-mediated assemblies

    J. Chen, Y. Hou, Q. Zhou, H. Zhang and D. Liu, CrystEngComm, 2017, Advance Article , DOI: 10.1039/C7CE00573C

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