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Homochiral porous coordination polymers with a rare utk topology and two types of uniform channels for enantioseparation

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Abstract

A pair of enantiopure chiral porous coordination polymers (PCPs) with a rare utk topology were prepared using derivatives of L-/D-alanine and Zn(CH3COO)2·2H2O. The framework integrated two types of parallel and uniform 1D channels that were constructed by self-stranding of three equal helical chains and a single helical chain. Among them, the right-handed PCP D-NTU-18 showed enhanced enantioseparation towards racemic 1-phenyl-1-propanol.

Graphical abstract: Homochiral porous coordination polymers with a rare utk topology and two types of uniform channels for enantioseparation

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Publication details

The article was received on 17 Mar 2017, accepted on 07 Apr 2017 and first published on 07 Apr 2017


Article type: Communication
DOI: 10.1039/C7CE00522A
Citation: CrystEngComm, 2017, Advance Article
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    Homochiral porous coordination polymers with a rare utk topology and two types of uniform channels for enantioseparation

    C. Zou, Q. Li, F. Cheng, H. Wang, J. Duan and W. Jin, CrystEngComm, 2017, Advance Article , DOI: 10.1039/C7CE00522A

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