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A new methyl-embedded (3,36)-connected txt-type metal–organic framework exhibiting high H2 adsorption property

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Abstract

A new methyl-embedded (3,36)-connected txt-type metal–organic framework, {Cu2(DCPEMP)·H2O}n (NJFU-4, H4DCPEMP = 3,5-bis(3,5-dicarboxylphenylethynyl)-4-methylpyridine), was solvothermally synthesized and structurally characterized, which exhibits a BET surface area of 2160 m2 g−1, high stability and high H2 uptake capacity (2.61 wt% at 1 bar and 77 K).

Graphical abstract: A new methyl-embedded (3,36)-connected txt-type metal–organic framework exhibiting high H2 adsorption property

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Publication details

The article was received on 05 Mar 2017, accepted on 10 May 2017 and first published on 10 May 2017


Article type: Communication
DOI: 10.1039/C7CE00461C
Citation: CrystEngComm, 2017, Advance Article
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    A new methyl-embedded (3,36)-connected txt-type metal–organic framework exhibiting high H2 adsorption property

    L. Du, J. Zhang, Z. Lu, J. Duan and L. Xu, CrystEngComm, 2017, Advance Article , DOI: 10.1039/C7CE00461C

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