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Synthesis, structure, characterization and multifunctional properties of a family of rare earth organic frameworks

Abstract

A series of isomorphism 3D layered rare earth hydroxide (LREH) frameworks: RE3(OH)7(1,5-NDS) (RE = Y (1), Gd (2), Er (3), Yb (4); 1,5-NDS = 1,5-naphthalenedisulfonate) have been synthesized under hydrothermal condition. The crystal structure, thermal stability, photoluminescence and magnetic properties of these compounds have been investigated. The results demonstrate that the compounds are highly stable even at 351 °C and emit strong purple fluorescence whose colour can be tuned by the coordinated rare earth ions. Their magnetic susceptibilities have also been measured, leading the compounds to be promising multifunctional materials.

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Publication details

The article was received on 27 Jan 2017, accepted on 13 Mar 2017, published on 17 Mar 2017 and first published online on 17 Mar 2017


Article type: Paper
DOI: 10.1039/C7CE00202E
Citation: CrystEngComm, 2017, Accepted Manuscript
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    Synthesis, structure, characterization and multifunctional properties of a family of rare earth organic frameworks

    H. Li, T. Sheng, Z. Xue, X. Zhu, S. Hu, Y. Wen, R. Fu, C. Zhuo and X. Wu, CrystEngComm, 2017, Accepted Manuscript , DOI: 10.1039/C7CE00202E

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