Issue 5, 2017
From the journal:

CrystEngComm

Crystal structure and magnetic properties of two manganese(ii) homometallic coordination polymers†

Bin Xia,a   Kai Wang,a   Qing-Lun Wang, ORCID logo *a   Yue Ma,a   Yu-Zhang Tong*b  and  Dai-Zheng Liaob  

* Corresponding authors

a Department of Chemistry, Nankai University, Tianjin, PR China
E-mail: wangql@nankai.edu.cn

b Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, PR China

Abstract

Two manganese(II) homometallic coordination polymers of compositions [Mn(CN)2(pz)]n (1) and {[Mn4(CN)8(bpy)3(EtOH)1.14(H2O)0.86]·bpy}n (2) have been synthesized in an inert atmosphere. In these compounds, metal cyanide 2D layers are linked into 3D networks by pillar ligands. Antiferromagnetic coupling occurs between Mn(II) ions and the antiferromagnetic ordering in these compounds is observed with Neel temperatures (TN) of 20.0 K in complex 1 and 8.0 K in complex 2.

Graphical abstract: Crystal structure and magnetic properties of two manganese(ii) homometallic coordination polymers

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Article information

DOI
https://doi.org/10.1039/C6CE02178F
Article type
Paper
Submitted
15 Oct 2016
Accepted
20 Dec 2016
First published
20 Dec 2016

CrystEngComm, 2017,19, 811-816

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Crystal structure and magnetic properties of two manganese(II) homometallic coordination polymers

B. Xia, K. Wang, Q. Wang, Y. Ma, Y. Tong and D. Liao, CrystEngComm, 2017, 19, 811 DOI: 10.1039/C6CE02178F

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