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Ambient chemical fixation of CO2 using a highly efficient heterometallic helicate catalyst system

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Abstract

Two novel heptanuclear 3d–4f helicates have been synthesized and characterized. The helicates act as catalysts and show high catalytic activity for the coupling of CO2 and epoxides to obtain cyclic carbonates with a wide substrate scope at ambient temperature and pressure.

Graphical abstract: Ambient chemical fixation of CO2 using a highly efficient heterometallic helicate catalyst system

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Publication details

The article was received on 27 Nov 2017, accepted on 21 Dec 2017 and first published on 21 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC09092G
Citation: Chem. Commun., 2018, Advance Article
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    Ambient chemical fixation of CO2 using a highly efficient heterometallic helicate catalyst system

    L. Wang, C. Xu, Q. Han, X. Tang, P. Zhou, R. Zhang, G. Gao, B. Xu, W. Qin and W. Liu, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC09092G

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