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Thiazolium salt-catalyzed C–C triple bond cleavage for accessing substituted 1-naphthols via benzannulation

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Abstract

The first thiazolium salt-catalyzed C–C triple bond cleavage of benzene-linked allene-ynes has been established. The reaction pathway involves [2+2] cycloaddition and ring-opening of in situ generated cyclobutenes with H2O under mild and convenient conditions, and provides practical access to substituted 1-naphthols with potentially valuable applications.

Graphical abstract: Thiazolium salt-catalyzed C–C triple bond cleavage for accessing substituted 1-naphthols via benzannulation

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Publication details

The article was received on 15 Nov 2017, accepted on 29 Nov 2017 and first published on 30 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC08792F
Citation: Chem. Commun., 2018, Advance Article
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    Thiazolium salt-catalyzed C–C triple bond cleavage for accessing substituted 1-naphthols via benzannulation

    P. Zhou, J. Wang, T. Zhang, G. Li, W. Hao, S. Tu and B. Jiang, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC08792F

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