Jump to main content
Jump to site search


Synthesis and reactions of 4H-1,4-telluraborine

Author affiliations

Abstract

The B(C6F5)3-catalyzed reaction of the 1,4-telluraborine, Te(PhC[double bond, length as m-dash]C(C6F5))2BOCH2Ph 2 with PhSiH3 gives Te(PhC[double bond, length as m-dash]C(C6F5))2BH 3. Compound 3 acts as a synthetic precursor to Te(PhC[double bond, length as m-dash]C(C6F5))2BCl 4 and Te(PhC[double bond, length as m-dash]C(C6F5))2B(THF)(O3SCF3) 5. In addition, 3 undergoes reactions with alkenes, alkynes, ketones and aldehydes to give a series of hydroboration products, 6–16.

Graphical abstract: Synthesis and reactions of 4H-1,4-telluraborine

Back to tab navigation

Supplementary files

Publication details

The article was received on 14 Nov 2017, accepted on 06 Dec 2017 and first published on 06 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08765A
Citation: Chem. Commun., 2018, Advance Article
  •   Request permissions

    Synthesis and reactions of 4H-1,4-telluraborine

    F. A. Tsao and D. W. Stephan, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC08765A

Search articles by author

Spotlight

Advertisements