Jump to main content
Jump to site search

Issue 2, 2018
Previous Article Next Article

Chiral amine-catalyzed asymmetric conjugate addition of aldehydes to α-phenylselenoenones as formal Z-allylating agents

Author affiliations

Abstract

α-Selenoenones could be employed as Z-allyl precursors in the chiral amine-catalyzed asymmetric conjugate addition of aldehydes. The obtained formal allylation product, a Z-olefin having a sulfonate leaving group, was employed as a synthetically useful chiral alkylating agent.

Graphical abstract: Chiral amine-catalyzed asymmetric conjugate addition of aldehydes to α-phenylselenoenones as formal Z-allylating agents

Back to tab navigation

Supplementary files

Publication details

The article was received on 11 Nov 2017, accepted on 01 Dec 2017 and first published on 01 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08691A
Citation: Chem. Commun., 2018,54, 176-179
  •   Request permissions

    Chiral amine-catalyzed asymmetric conjugate addition of aldehydes to α-phenylselenoenones as formal Z-allylating agents

    T. Kano, H. Maruyama, C. Homma and K. Maruoka, Chem. Commun., 2018, 54, 176
    DOI: 10.1039/C7CC08691A

Search articles by author

Spotlight

Advertisements