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Chiral amine-catalyzed asymmetric conjugate addition of aldehydes to α-phenylselenoenones as formal Z-allylating agents

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Abstract

α-Selenoenones could be employed as Z-allyl precursors in the chiral amine-catalyzed asymmetric conjugate addition of aldehydes. The obtained formal allylation product, a Z-olefin having a sulfonate leaving group, was employed as a synthetically useful chiral alkylating agent.

Graphical abstract: Chiral amine-catalyzed asymmetric conjugate addition of aldehydes to α-phenylselenoenones as formal Z-allylating agents

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Publication details

The article was received on 11 Nov 2017, accepted on 01 Dec 2017 and first published on 01 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08691A
Citation: Chem. Commun., 2018, Advance Article
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    Chiral amine-catalyzed asymmetric conjugate addition of aldehydes to α-phenylselenoenones as formal Z-allylating agents

    T. Kano, H. Maruyama, C. Homma and K. Maruoka, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC08691A

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