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Hexacyano-[3]-radialene anion-radical salts: a promising family of highly soluble p-dopants

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Abstract

Organic and inorganic salts of the hexacyano-[3]-radialene anion-radical are readily available and thermally stable compounds (up to ∼180 °C). The tetrabutylammonium salt exhibits an extremely high solubility in a range of solvents (>300 mg l−1 in CHCl3) and acts as an efficient p-dopant for poly(3-hexylthiophene) to provide composite films with a conductivity above 2 S cm−1.

Graphical abstract: Hexacyano-[3]-radialene anion-radical salts: a promising family of highly soluble p-dopants

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Publication details

The article was received on 10 Nov 2017, accepted on 06 Dec 2017 and first published on 06 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08671G
Citation: Chem. Commun., 2018, Advance Article
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    Hexacyano-[3]-radialene anion-radical salts: a promising family of highly soluble p-dopants

    Y. Karpov, N. Kiriy, M. Al-Hussein, M. Hambsch, T. Beryozkina, V. Bakulev, S. C. B. Mannsfeld, B. Voit and A. Kiriy, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC08671G

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