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Efficient synthesis of benzocyclotrimer analogues by Negishi cross-coupling and intramolecular nucleophilic substitution

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Abstract

We report a new and efficient synthetic strategy that allows access to flexible and functionalized benzocyclotrimers under mild conditions and in few steps. The Negishi cross-coupling reaction was used for the C–C bond formation, whereas intramolecular O-alkylations provided the oxepane rings.

Graphical abstract: Efficient synthesis of benzocyclotrimer analogues by Negishi cross-coupling and intramolecular nucleophilic substitution

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Publication details

The article was received on 08 Nov 2017, accepted on 04 Dec 2017 and first published on 04 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08616D
Citation: Chem. Commun., 2018, Advance Article
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    Efficient synthesis of benzocyclotrimer analogues by Negishi cross-coupling and intramolecular nucleophilic substitution

    J. Borges-González and T. Martín, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC08616D

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