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Aluminium-mediated carbon-carbon coupling of an isonitrile

Abstract

Cp*Al reacts with diphenylacetylene to form a Cp*-substituted 1,4-dialuminacyclohexene. The dialuminacyclohexene reacts with four equivalents of an isonitrile to couple the terminal carbon atoms, forming 6 new carbon-carbon bonds and resulting in a zitterionic diamide ligand which contains a carbocationic backbone.

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Publication details

The article was received on 01 Nov 2017, accepted on 07 Dec 2017 and first published on 07 Dec 2017


Article type: Communication
DOI: 10.1039/C7CC08415C
Citation: Chem. Commun., 2017, Accepted Manuscript
  • Open access: Creative Commons BY-NC license
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    Aluminium-mediated carbon-carbon coupling of an isonitrile

    M. J. Cowley, S. J. Urwin and G. S. Nichol, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC08415C

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