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Alkyl radical triggered in situ SO2-capture cascades

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Abstract

An unprecedented in situ SO2-capture cascade triggered by alkyl radicals has been documented herein. Mechanistic investigations suggest that, triggered by alkyl radicals, SO2 was released in situ and subsequently fixed into polycyclic small molecules. A wide range of alkylsulfonyl substituted polycyclic compounds were easily prepared with high yields and good functional group tolerability.

Graphical abstract: Alkyl radical triggered in situ SO2-capture cascades

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Publication details

The article was received on 31 Oct 2017, accepted on 14 Nov 2017 and first published on 21 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC08362A
Citation: Chem. Commun., 2017, Advance Article
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    Alkyl radical triggered in situ SO2-capture cascades

    X. Su, H. Huang, W. Hong, J. Cui, M. Yu and Y. Li, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC08362A

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