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Homogeneous electrocatalytic water oxidation at neutral pH by a robust trinuclear copper(II)-substituted polyoxometalate

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Abstract

[(α-SbW9O33)2Cu3(H2O)3]12− (1) was tested as the first copper-containing polyoxometalate catalyst for O2 production via electrocatalytic water oxidation at a neutral pH. Multiple lines of experimental evidence confirm that catalytic water oxidation by 1 takes place in the absence of any heterogeneous species generated in situ. The catalytic capabilities of 1 and equal amounts of CuCl2 are completely different for electrocatalytic water oxidation behavior.

Graphical abstract: Homogeneous electrocatalytic water oxidation at neutral pH by a robust trinuclear copper(ii)-substituted polyoxometalate

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Publication details

The article was received on 27 Oct 2017, accepted on 30 Nov 2017 and first published on 30 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC08301G
Citation: Chem. Commun., 2018, Advance Article
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    Homogeneous electrocatalytic water oxidation at neutral pH by a robust trinuclear copper(II)-substituted polyoxometalate

    L. Yu, J. Lin, M. Zheng, M. Chen and Y. Ding, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C7CC08301G

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