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Issue 99, 2017
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The role of symmetry breaking in the structural trapping of light-induced excited spin states

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Abstract

Light-Induced Excited Spin State Trapping (LIESST) data are reported for seven isostructural solvate salts from the iron(II)/2,6-di(pyrazol-1-yl)pyridine family. A complicated relationship between their spin-crossover T1/2 and T(LIESST) values may reflect low-temperature thermal and light-induced symmetry breaking, which is shown by one of the compounds but not by two others.

Graphical abstract: The role of symmetry breaking in the structural trapping of light-induced excited spin states

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Publication details

The article was received on 16 Oct 2017, accepted on 20 Nov 2017 and first published on 24 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC07990G
Citation: Chem. Commun., 2017,53, 13268-13271
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    The role of symmetry breaking in the structural trapping of light-induced excited spin states

    R. Kulmaczewski, E. Trzop, L. J. Kershaw Cook, E. Collet, G. Chastanet and M. A. Halcrow, Chem. Commun., 2017, 53, 13268
    DOI: 10.1039/C7CC07990G

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