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Ruthenium-catalyzed olefinic C–H alkenylation of enol-carbamates: highly stereo-selective synthesis of (Z,Z) and (Z,E)-butadienes

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Abstract

Cross-coupling reactions of enol carbamates with alkynes or alkenes are reported, using an inexpensive ruthenium catalyst. With the assistance of the directing group OCONMe2, the protocols provide mild, stereo-selective and efficient routes for the preparation of valuable (Z,Z) and (Z,E)-butadiene skeletons.

Graphical abstract: Ruthenium-catalyzed olefinic C–H alkenylation of enol-carbamates: highly stereo-selective synthesis of (Z,Z) and (Z,E)-butadienes

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Publication details

The article was received on 08 Oct 2017, accepted on 10 Nov 2017 and first published on 10 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC07777G
Citation: Chem. Commun., 2017, Advance Article
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    Ruthenium-catalyzed olefinic C–H alkenylation of enol-carbamates: highly stereo-selective synthesis of (Z,Z) and (Z,E)-butadienes

    T. Li, J. Zhang, C. Yu, X. Lu, L. Xu and G. Zhong, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC07777G

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