Issue 95, 2017

Gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes

Abstract

An unprecedented gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes has been developed, providing eight-membered heterocycles in good to excellent yields. Deuterium labeling and control experiments reveal the possible reaction mechanism for this annulation.

Graphical abstract: Gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes

Supplementary files

Article information

Article type
Communication
Submitted
28 Sep 2017
Accepted
08 Nov 2017
First published
08 Nov 2017

Chem. Commun., 2017,53, 12770-12773

Gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes

S. Peng, D. Ji and J. Sun, Chem. Commun., 2017, 53, 12770 DOI: 10.1039/C7CC07554E

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