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Gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes

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Abstract

An unprecedented gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes has been developed, providing eight-membered heterocycles in good to excellent yields. Deuterium labeling and control experiments reveal the possible reaction mechanism for this annulation.

Graphical abstract: Gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes

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Publication details

The article was received on 28 Sep 2017, accepted on 08 Nov 2017 and first published on 08 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC07554E
Citation: Chem. Commun., 2017, Advance Article
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    Gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes

    S. Peng, D. Ji and J. Sun, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC07554E

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