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Palladium-catalyzed denitrogenative functionalizations of benzotriazoles with alkenes and 1,3-dienes

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Abstract

Pd-Catalyzed denitrogenative functionalizations of benzotriazoles with alkenes and 1,3-dienes have been developed, which enable the rapid access of diverse ortho-amino styrenes and 2-vinylindolines, respectively. This study shows the great potential of benzotriazoles as a [1C]-synthon in cross-coupling reactions and an aza-[3C]-synthon in cycloaddition reactions.

Graphical abstract: Palladium-catalyzed denitrogenative functionalizations of benzotriazoles with alkenes and 1,3-dienes

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Publication details

The article was received on 27 Sep 2017, accepted on 09 Oct 2017 and first published on 10 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC07543J
Citation: Chem. Commun., 2017, Advance Article
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    Palladium-catalyzed denitrogenative functionalizations of benzotriazoles with alkenes and 1,3-dienes

    Y. Wang, Y. Li, Y. Fan, Z. Wang and Y. Tang, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC07543J

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