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From Helix to Helical Pores: Solid-state Crystalline Conversions Triggered by Gas-Solid Reactions

Abstract

Two one-dimensional (1D) helical coordination polymers, CuBIm-Cl and CuBIm-Br (BIm = 1,2-bis((5H-imidazol-4-yl)-methylene)hydrazine), are constructed from Cu2+ ions, halides and mono-deprotonated BIm. Solid-state crystalline conversions of CuBIm-Cl and CuBIm-Br to a gyrodial metal-organic framework (MOF) STU-3 which is composed of Cu ions and Bim ligands are observed through a gas-solid reaction, where the gas is methylamine.

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Publication details

The article was received on 27 Sep 2017, accepted on 08 Nov 2017 and first published on 08 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC07510C
Citation: Chem. Commun., 2017, Accepted Manuscript
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    From Helix to Helical Pores: Solid-state Crystalline Conversions Triggered by Gas-Solid Reactions

    J. Liu, J. Du, Y. Wu, Y. Zhao, X. Zhou and D. Li, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC07510C

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