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Issue 92, 2017
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Versatile palladium-catalyzed double carbonylation of aryl bromides

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Abstract

A versatile palladium-catalyzed double carbonylation of aryl bromides has been developed. Using Pd(OAc)2/BuPAd2 as the catalyst system and DBU as the base, under relatively low CO pressure, various α-ketoamides were produced in good yields. In order to get insight into the reaction pathway, real time NMR studies were performed as well and a correlated reaction mechanism is been given.

Graphical abstract: Versatile palladium-catalyzed double carbonylation of aryl bromides

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Publication details

The article was received on 22 Sep 2017, accepted on 13 Oct 2017 and first published on 18 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC07412C
Citation: Chem. Commun., 2017,53, 12422-12425
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    Versatile palladium-catalyzed double carbonylation of aryl bromides

    C. Shen, C. Fink, G. Laurenczy, P. J. Dyson and X. Wu, Chem. Commun., 2017, 53, 12422
    DOI: 10.1039/C7CC07412C

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