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Alkylideneborate Zwitterions and C-C Coupling by Atypical Diboration of Electron-Rich Alkynes

Abstract

The combination of electron-rich diaminoalkynes and ditopic Lewis acids diboranes(4) leads to unusual uncatalysed diboration reactions involving internal Lewis adduct and zwitterion formation and C-C bond formation.

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Publication details

The article was accepted on 10 Oct 2017 and first published on 11 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC07409C
Citation: Chem. Commun., 2017, Accepted Manuscript
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    Alkylideneborate Zwitterions and C-C Coupling by Atypical Diboration of Electron-Rich Alkynes

    J. Böhnke, H. Braunschweig, A. Deißenberger, T. Dellermann, R. D. Dewhurst, J. O. C. Jimenez-Halla, S. Kachel, H. Kelch and D. Prieschl, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC07409C

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