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Issue 87, 2017
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Double C–S bond formation via C–H bond functionalization: synthesis of benzothiazoles and naphtho[2,1-d]thiazoles from N-substituted arylamines and elemental sulfur

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Abstract

A novel, atom economic, and environmentally friendly method for the synthesis of 2-substituted benzothiazoles and 2-substituted naphtho[2,1-d]thiazoles from N-substituted arylamines and elemental sulfur has been developed under metal-free conditions. The reaction underwent the process of double C–S bond formation through C–H bond functionalization.

Graphical abstract: Double C–S bond formation via C–H bond functionalization: synthesis of benzothiazoles and naphtho[2,1-d]thiazoles from N-substituted arylamines and elemental sulfur

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Publication details

The article was received on 21 Sep 2017, accepted on 09 Oct 2017 and first published on 09 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC07366F
Citation: Chem. Commun., 2017,53, 11917-11920
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    Double C–S bond formation via C–H bond functionalization: synthesis of benzothiazoles and naphtho[2,1-d]thiazoles from N-substituted arylamines and elemental sulfur

    X. Zhu, Y. Yang, G. Xiao, J. Song, Y. Liang and G. Deng, Chem. Commun., 2017, 53, 11917
    DOI: 10.1039/C7CC07366F

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