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Interception of amide ylides with sulfonamides: synthesis of (E)-N-sulfonyl amidines catalyzed by Zn(OTf)2

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Abstract

Through the interception of amide ylides with sulfonamides, we herein report the first general example of an intermolecular condensation reaction between sulfonamides and amides. Beyond formamides, this approach was successfully applied to a variety of lactams and linear amides, giving rise to a broad array of (E)-N-sulfonyl amidines.

Graphical abstract: Interception of amide ylides with sulfonamides: synthesis of (E)-N-sulfonyl amidines catalyzed by Zn(OTf)2

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Publication details

The article was received on 21 Sep 2017, accepted on 22 Nov 2017 and first published on 22 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC07364J
Citation: Chem. Commun., 2017, Advance Article
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    Interception of amide ylides with sulfonamides: synthesis of (E)-N-sulfonyl amidines catalyzed by Zn(OTf)2

    J. Chen, W. Long, S. Fang, Y. Yang and X. Wan, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC07364J

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