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Issue 84, 2017
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Visible-light promoted γ-cyanoalkyl radical generation: three-component cyanopropylation/etherification of unactivated alkenes

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Abstract

A photoredox approach to generate distal cyano-substituted alkyl radicals through C–C bond cleavage of cyclobutanone oximes was developed. The radicals produced by this method were applied to three-component cyanopropylation/etherification of unactivated alkenes. Their reactions with diverse radical acceptors were also demonstrated.

Graphical abstract: Visible-light promoted γ-cyanoalkyl radical generation: three-component cyanopropylation/etherification of unactivated alkenes

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Publication details

The article was received on 21 Sep 2017, accepted on 28 Sep 2017 and first published on 28 Sep 2017


Article type: Communication
DOI: 10.1039/C7CC07347J
Citation: Chem. Commun., 2017,53, 11544-11547
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    Visible-light promoted γ-cyanoalkyl radical generation: three-component cyanopropylation/etherification of unactivated alkenes

    L. Li, H. Chen, M. Mei and L. Zhou, Chem. Commun., 2017, 53, 11544
    DOI: 10.1039/C7CC07347J

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