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Issue 93, 2017
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Palladium-catalyzed direct sulfonylation of C–H bonds with the insertion of sulfur dioxide

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Abstract

A palladium-catalyzed direct sulfonylation of C–H bonds with the insertion of sulfur dioxide under mild conditions is reported. The sulfonylative couplings with the insertion of sulfur dioxide into C–H bonds are effective, and two classes of sulfonylative products are formed in moderate to good yields by the combination of radical chemistry and palladium-catalyzed C–H activation.

Graphical abstract: Palladium-catalyzed direct sulfonylation of C–H bonds with the insertion of sulfur dioxide

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The article was received on 17 Sep 2017, accepted on 31 Oct 2017 and first published on 01 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC07279A
Citation: Chem. Commun., 2017,53, 12548-12551
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    Palladium-catalyzed direct sulfonylation of C–H bonds with the insertion of sulfur dioxide

    H. Xia, Y. An, X. Zeng and J. Wu, Chem. Commun., 2017, 53, 12548
    DOI: 10.1039/C7CC07279A

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