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Silver-induced self-immolative Cl–F exchange fluorination of arylsulfur chlorotetrafluorides: synthesis of arylsulfur pentafluorides

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Abstract

A novel strategy for the synthesis of arylsulfur pentafluorides by silver carbonate-induced Cl–F exchange fluorination of arylsulfur chlorotetrafluorides is reported. This fluorination does not require any exogenous fluoride sources. Rather, the reaction proceeds via the self-immolation of the substrate Ar-SF4Cl.

Graphical abstract: Silver-induced self-immolative Cl–F exchange fluorination of arylsulfur chlorotetrafluorides: synthesis of arylsulfur pentafluorides

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Publication details

The article was received on 14 Sep 2017, accepted on 09 Oct 2017 and first published on 17 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC07222H
Citation: Chem. Commun., 2017, Advance Article
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    Silver-induced self-immolative Cl–F exchange fluorination of arylsulfur chlorotetrafluorides: synthesis of arylsulfur pentafluorides

    B. Cui, S. Jia, E. Tokunaga, N. Saito and N. Shibata, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC07222H

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