Issue 88, 2017
From the journal:

Chemical Communications

A direct access to heterobimetallic complexes by roll-over cyclometallation†

F. Schön,‡a   M. Leist,a   A. Neuba,b   J. Lang,ac   C. Braun,d   Y. Sun,a   G. Niedner-Schatteburg, ORCID logo ac   S. Bräse ORCID logo de  and  W. R. Thiel ORCID logo *a  

* Corresponding authors

a Fachbereich Chemie, TU Kaiserslautern, Erwin-Schrödinger-Str. 54, 67663 Kaiserslautern, Germany
E-mail: thiel@chemie.uni-kl.de

b Department Chemie, Universität Paderborn, Warburger Straße 100, 33098 Paderborn, Germany

c Forschungszentrum OPTIMAS, Technische Universität Kaiserslautern, 67663 Kaiserslautern, Germany

d Institute of Organic Chemistry, Karlsruhe Institute of Technology, Fritz-Haber-Weg 6, D-76131 Karlsruhe, Germany

e Institute of Toxicology and Genetics, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany

Abstract

Complexes of the type [Cp*Ir(N,N′)Cl]+ (N,N′ = 2-(2-dialkylaminopyrimidin-4-yl)pyrimidine) can undergo roll-over cyclometallation leading to a novel N,N′-donor site. Following this strategy heterobimetallic complexes including iridium(III) and a Group X metal centre in the oxidation state +II were achieved.

Graphical abstract: A direct access to heterobimetallic complexes by roll-over cyclometallation

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Article information

DOI
https://doi.org/10.1039/C7CC07119A
Article type
Communication
Submitted
12 Sep 2017
Accepted
11 Oct 2017
First published
12 Oct 2017

Chem. Commun., 2017,53, 12016-12019

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A direct access to heterobimetallic complexes by roll-over cyclometallation

F. Schön, M. Leist, A. Neuba, J. Lang, C. Braun, Y. Sun, G. Niedner-Schatteburg, S. Bräse and W. R. Thiel, Chem. Commun., 2017, 53, 12016 DOI: 10.1039/C7CC07119A

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