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Issue 88, 2017
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A direct access to heterobimetallic complexes by roll-over cyclometallation

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Abstract

Complexes of the type [Cp*Ir(N,N′)Cl]+ (N,N′ = 2-(2-dialkylaminopyrimidin-4-yl)pyrimidine) can undergo roll-over cyclometallation leading to a novel N,N′-donor site. Following this strategy heterobimetallic complexes including iridium(III) and a Group X metal centre in the oxidation state +II were achieved.

Graphical abstract: A direct access to heterobimetallic complexes by roll-over cyclometallation

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Publication details

The article was received on 12 Sep 2017, accepted on 11 Oct 2017 and first published on 12 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC07119A
Citation: Chem. Commun., 2017,53, 12016-12019
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    A direct access to heterobimetallic complexes by roll-over cyclometallation

    F. Schön, M. Leist, A. Neuba, J. Lang, C. Braun, Y. Sun, G. Niedner-Schatteburg, S. Bräse and W. R. Thiel, Chem. Commun., 2017, 53, 12016
    DOI: 10.1039/C7CC07119A

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