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Synthesis and EPR studies of the first water-soluble N@C60 derivative

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Abstract

The first water-soluble derivative of the paramagnetic endohedral fullerene N@C60 has been prepared through the covalent attachment of a single addend containing two permethylated β-cyclodextrin units to the surface of the carbon cage. The line width of the derivative's EPR signal is highly sensitive to both the nature of the solvent and the presence of Cu(II) ions in solution.

Graphical abstract: Synthesis and EPR studies of the first water-soluble N@C60 derivative

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Publication details

The article was received on 11 Sep 2017, accepted on 01 Nov 2017 and first published on 01 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC07106J
Citation: Chem. Commun., 2017, Advance Article
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    Synthesis and EPR studies of the first water-soluble N@C60 derivative

    S. P. Cornes, S. Zhou and K. Porfyrakis, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC07106J

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