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Issue 99, 2017
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A meta-selective-C–H alkenylation of phenol-derivatives employing a traceless organosilicon template

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Abstract

A traceless organosilicon template-directed meta-selective-C–H alkenylation of phenols was realized with good yields and high selectivities. The template was readily removable through F-promoted O–Si cleavage under extremely mild conditions or recyclable through a p-TSA catalyzed process. The product was successfully applied in the preparation of a series of meta-alkenylated aromatic compounds.

Graphical abstract: A meta-selective-C–H alkenylation of phenol-derivatives employing a traceless organosilicon template

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Publication details

The article was received on 11 Sep 2017, accepted on 09 Nov 2017 and first published on 17 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC07093D
Citation: Chem. Commun., 2017,53, 13209-13212
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    A meta-selective-C–H alkenylation of phenol-derivatives employing a traceless organosilicon template

    R. Mi, J. Sun, F. E. Kühn, M. Zhou and Z. Xu, Chem. Commun., 2017, 53, 13209
    DOI: 10.1039/C7CC07093D

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