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Issue 85, 2017
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Unprecedented magnetic behaviour in lanthanide-based ionic liquids

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Abstract

Ionic liquids containing lanthanide halide anions give the opportunity to investigate magnetic behaviour in non-ordered systems. Reported herein is the synthesis and characterization of ionic liquids containing a series of lanthanide halide anions, with the resulting materials displaying unusual behaviour below 50 K. Specifically, the ionic liquid structural glass formation appears to drive magnetic behaviour due to cluster formation of the anions during rapid cooling. This system presents a possible probe to study the dynamics of glass forming materials.

Graphical abstract: Unprecedented magnetic behaviour in lanthanide-based ionic liquids

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Publication details

The article was received on 12 Sep 2017, accepted on 02 Oct 2017 and first published on 11 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC07060H
Citation: Chem. Commun., 2017,53, 11682-11685
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    Unprecedented magnetic behaviour in lanthanide-based ionic liquids

    T. C. Monson, T. E. Stevens, J. L. Leger, J. L. Manson, K. S. Lovejoy, A. L. Newsham and R. E. Del Sesto, Chem. Commun., 2017, 53, 11682
    DOI: 10.1039/C7CC07060H

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