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Th(IV) and Ce(IV) Napthylsalophen Sandwich Complexes: Characterization of Unusual Thorium Fluorescence in Solution and Solid-state

Abstract

The synthesis, characterization, and electronic spectroscopy of two ML2 sandwich complexes, where M=Ce(IV) or Th(IV) and L=napthylsalophen2 are described. The ThL2 complex, unlike the isovalent CeL2, complex possesses unusual fluorescence properties in both solution and solid-state. These observations are explained with TD-DFT.

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Publication details

The article was received on 02 Sep 2017, accepted on 11 Oct 2017 and first published on 11 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC06868A
Citation: Chem. Commun., 2017, Accepted Manuscript
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    Th(IV) and Ce(IV) Napthylsalophen Sandwich Complexes: Characterization of Unusual Thorium Fluorescence in Solution and Solid-state

    E. E. Hardy, K. M. Wyss, J. D. Gorden, I. R. Ariyarathna, E. Miliordos and A. E. V. Gorden, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC06868A

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