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Issue 92, 2017
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Enantioselective syntheses of atropisomers featuring a five-membered ring

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Abstract

Atropisomerism is a fundamental property of molecules featuring a hindered rotation around a chemical bond. If six-membered ring biaryl or heterobiaryl atropisomers are the most popular ones, the focus of this feature article will be put on less common and more challenging five-membered ring containing atropisomers displaying either a stereogenic CN or CC bond. After an historical background, a description of the latest flourishing enantioselective strategies for the construction of this attractive family of atropisomers will be presented.

Graphical abstract: Enantioselective syntheses of atropisomers featuring a five-membered ring

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Publication details

The article was received on 01 Sep 2017, accepted on 14 Oct 2017 and first published on 16 Oct 2017


Article type: Feature Article
DOI: 10.1039/C7CC06863H
Citation: Chem. Commun., 2017,53, 12385-12393
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    Enantioselective syntheses of atropisomers featuring a five-membered ring

    D. Bonne and J. Rodriguez, Chem. Commun., 2017, 53, 12385
    DOI: 10.1039/C7CC06863H

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