Jump to main content
Jump to site search

Issue 89, 2017
Previous Article Next Article

A DFT study unveils the secret of how H2 is activated in the N-formylation of amines with CO2 and H2 catalyzed by Ru(II) pincer complexes in the absence of exogenous additives

Author affiliations

Abstract

We herein report a new H2 activation mechanism to elucidate the N-formylation of amines with CO2 and H2, catalyzed by Ru(II) pincer complexes in the absence of exogenous additives. Furthermore, we show that the mechanism could be applied to other types of Ru(II) pincer complexes and computed iron analogs.

Graphical abstract: A DFT study unveils the secret of how H2 is activated in the N-formylation of amines with CO2 and H2 catalyzed by Ru(ii) pincer complexes in the absence of exogenous additives

Back to tab navigation

Supplementary files

Publication details

The article was received on 30 Aug 2017, accepted on 05 Oct 2017 and first published on 05 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC06795J
Citation: Chem. Commun., 2017,53, 12148-12151
  •   Request permissions

    A DFT study unveils the secret of how H2 is activated in the N-formylation of amines with CO2 and H2 catalyzed by Ru(II) pincer complexes in the absence of exogenous additives

    Y. Lu, Z. Liu, J. Guo, S. Qu, R. Zhao and Z. Wang, Chem. Commun., 2017, 53, 12148
    DOI: 10.1039/C7CC06795J

Search articles by author

Spotlight

Advertisements