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Efficient Ni-catalyzed conversion of phenols protected with 2,4,6-trichloro-1,3,5-triazine (TCT) to olefins

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Abstract

An efficient Ni(COD)2/dppf catalyzed olefination of Ar–O–TCT as synthetic equivalents of aryl halides is described. Activation of C–O bonds in phenols as readily available compounds was achieved with 2,4,6-trichloro-1,3,5-triazine (TCT). This method provides practical access to 1,2-disubstituted olefins in high yields and high functional group compatibility.

Graphical abstract: Efficient Ni-catalyzed conversion of phenols protected with 2,4,6-trichloro-1,3,5-triazine (TCT) to olefins

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Publication details

The article was received on 27 Aug 2017, accepted on 06 Nov 2017 and first published on 07 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC06717H
Citation: Chem. Commun., 2017, Advance Article
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    Efficient Ni-catalyzed conversion of phenols protected with 2,4,6-trichloro-1,3,5-triazine (TCT) to olefins

    E. Etemadi-Davan and N. Iranpoor, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC06717H

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