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A cluster-based mesoporous Ti-MOF with sodalite supercages

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Abstract

The cooperative assembly of a hexagonal column shaped [Ti6O6][iPrO]66+ cluster and rhomboid Cu2I2 dimers using isonicotinic acid results in an unprecedented three-dimensional (3D) highly crystalline cluster-based Ti-MOF that features both giant sodalite cages with an inner diameter of 2.8 × 3.2 nm2 and 3D open square channels.

Graphical abstract: A cluster-based mesoporous Ti-MOF with sodalite supercages

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Publication details

The article was received on 24 Aug 2017, accepted on 01 Oct 2017 and first published on 02 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC06652J
Citation: Chem. Commun., 2017, Advance Article
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    A cluster-based mesoporous Ti-MOF with sodalite supercages

    C. Wang, C. Liu, X. He and Z. Sun, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC06652J

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