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The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks

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Abstract

A straightforward slippage strategy has been used for the synthesis of three [2]rotaxane building blocks that all contain an ammonium template for the dibenzo-24-crown-8 macrocycle and an N-hydroxysuccinimide end. The kinetic rate of the slipping-on process proved to be highly dependent on both the length and flexibility of the thread.

Graphical abstract: The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks

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Publication details

The article was received on 22 Aug 2017, accepted on 12 Sep 2017 and first published on 12 Sep 2017


Article type: Communication
DOI: 10.1039/C7CC06598A
Citation: Chem. Commun., 2017, Advance Article
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    The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks

    B. Riss-Yaw, C. Clavel, Ph. Laurent and F. Coutrot, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC06598A

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