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Reversible regulating of crystal structures based on isomerization of phenylhydrazones

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Abstract

Reversible crystal transformation for phenylhydrazones 1 between the orthorhombic microporous 1-E crystal and monoclinic herringbone 1-Z crystal induced by light and heating has been demonstrated. Other than the inherent single-molecular photoreactivity, the weak intermolecular interactions and loose stacking of porous 1-E crystal favor the efficient solid-state photoisomerization.

Graphical abstract: Reversible regulating of crystal structures based on isomerization of phenylhydrazones

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Publication details

The article was received on 15 Aug 2017, accepted on 23 Oct 2017 and first published on 23 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC06374A
Citation: Chem. Commun., 2017, Advance Article
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    Reversible regulating of crystal structures based on isomerization of phenylhydrazones

    L. Ma, Z. Yuan, Z. Huang, J. Jin, D. Cao, R. Guan, Q. Chen and X. Sun, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC06374A

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