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Issue 83, 2017
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Stepwise engineering of pore environments and enhancement of CO2/R22 adsorption capacity through dynamic spacer installation and functionality modification

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Abstract

Through stepwise post-synthetic spacer insertion and click reactions, six Zr-MOFs with different types and amounts of functional groups have been constructed based on proto-MOF PCN-700. Their gas adsorption capacities and selectivities have been greatly improved and finely tuned, demonstrating the combinatorial effect of pore surface modification and pore space partition.

Graphical abstract: Stepwise engineering of pore environments and enhancement of CO2/R22 adsorption capacity through dynamic spacer installation and functionality modification

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Publication details

The article was received on 14 Aug 2017, accepted on 14 Sep 2017 and first published on 18 Sep 2017


Article type: Communication
DOI: 10.1039/C7CC06352K
Citation: Chem. Commun., 2017,53, 11403-11406
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    Stepwise engineering of pore environments and enhancement of CO2/R22 adsorption capacity through dynamic spacer installation and functionality modification

    C. Chen, Q. Qiu, C. Cao, M. Pan, H. Wang, J. Jiang, Z. Wei, K. Zhu, G. Li and C. Su, Chem. Commun., 2017, 53, 11403
    DOI: 10.1039/C7CC06352K

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