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Issue 80, 2017
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Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl

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Abstract

The oxidative carbonylation of ToMCoMe (1; ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) involves its rapid, reversible reaction with CO to form ToMCo{C(O)Me}CO (2) followed by rapid reaction with O2 yielding ToMCoOAc (3), in contrast to the slow direct carboxylation of ToMCoMe by CO2.

Graphical abstract: Rapid and ordered carbonylation and oxygenation of a cobalt(ii) methyl

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Publication details

The article was received on 13 Aug 2017, accepted on 15 Sep 2017 and first published on 15 Sep 2017


Article type: Communication
DOI: 10.1039/C7CC06339C
Citation: Chem. Commun., 2017,53, 11020-11023
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    Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl

    R. R. Reinig, E. L. Fought, A. Ellern, T. L. Windus and A. D. Sadow, Chem. Commun., 2017, 53, 11020
    DOI: 10.1039/C7CC06339C

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