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Facile insertion of a cyclic alkyl(amino) carbene carbon into the B–B bond of diboron(4) reagents

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Abstract

We report herein the room temperature insertion of the carbene carbon atom of the cyclic (alkyl)(amino) carbene cAACMe into the B–B single bonds of the diboron(4) compounds B2pin2, B2cat2, B2neop2, and B2eg2 (pin = pinacolato, cat = catecholato, neop = neopentylglycolato, eg = ethyleneglycolato).

Graphical abstract: Facile insertion of a cyclic alkyl(amino) carbene carbon into the B–B bond of diboron(4) reagents

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Publication details

The article was received on 11 Aug 2017, accepted on 04 Oct 2017 and first published on 04 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC06302D
Citation: Chem. Commun., 2017, Advance Article
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    Facile insertion of a cyclic alkyl(amino) carbene carbon into the B–B bond of diboron(4) reagents

    A. F. Eichhorn, L. Kuehn, T. B. Marder and U. Radius, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC06302D

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