Issue 78, 2017

Catalytic domino amination and oxidative coupling of gold acetylides and isolation of key vinylene digold intermediates as a new class of ditopic N-heterocyclic carbene complexes

Abstract

A catalytic domino amination and oxidative coupling of in situ prepared gold acetylides has been developed for the synthesis of abnormal NHC (aNHC) gold complexes, and key vinylene digold intermediates are isolated and structurally characterized.

Graphical abstract: Catalytic domino amination and oxidative coupling of gold acetylides and isolation of key vinylene digold intermediates as a new class of ditopic N-heterocyclic carbene complexes

Supplementary files

Article information

Article type
Communication
Submitted
03 Aug 2017
Accepted
12 Sep 2017
First published
12 Sep 2017

Chem. Commun., 2017,53, 10835-10838

Catalytic domino amination and oxidative coupling of gold acetylides and isolation of key vinylene digold intermediates as a new class of ditopic N-heterocyclic carbene complexes

H. Chen, J. Wang, Z. Hu, S. Xu, M. Shi and J. Zhang, Chem. Commun., 2017, 53, 10835 DOI: 10.1039/C7CC06069F

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