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An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides

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Abstract

We describe the synthesis of an ambiphilic phosphine/H-bond donor ligand featuring a trifluoroacetamide functionality, its coordination to gold(I) chloride, and its application as a self-activating catalyst for the cyclization of propargylamides.

Graphical abstract: An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides

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Publication details

The article was received on 03 Aug 2017, accepted on 22 Nov 2017 and first published on 22 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC06065C
Citation: Chem. Commun., 2017, Advance Article
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    An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides

    S. Sen and F. P. Gabbaï, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC06065C

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