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Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs

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Abstract

A siloxane-based hexacarboxylic acid (L1-H6) has been prepared and applied in MOF construction. L1-H6 itself crystallizes as an unusual interpenetrated 3D hydrogen-bonded framework. Reaction of L1-H6 with Zn(II) gave IMP-18 – a 3D MOF incorporating Si–O–Si functionality. Cleavage of L1-H6 gives a silanol-based triacid which is shown to give a coordination polymer (IMP-19) with Zn(II).

Graphical abstract: Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs

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Publication details

The article was received on 01 Aug 2017, accepted on 22 Sep 2017 and first published on 06 Nov 2017


Article type: Communication
DOI: 10.1039/C7CC06022J
Citation: Chem. Commun., 2017, Advance Article
  • Open access: Creative Commons BY license
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    Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs

    L. C. Delmas, P. N. Horton, A. J. P. White, S. J. Coles, P. D. Lickiss and R. P. Davies, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC06022J

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