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Issue 70, 2017
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Hysteretic spin crossover driven by anion conformational change

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Abstract

A new air stable FeIII spin crossover (SCO) complex has been synthesized. The compound undergoes abrupt SCO near room temperature with T1/2 (↓) = 244 K and T1/2 (↑) = 278 K. Structural studies of the complex in the high spin and low spin state show that the strong cooperativity and thus the wide hysteresis is driven by an unprecedented anionic conformational change.

Graphical abstract: Hysteretic spin crossover driven by anion conformational change

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Publication details

The article was received on 01 Aug 2017, accepted on 14 Aug 2017 and first published on 14 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC05998A
Citation: Chem. Commun., 2017,53, 9801-9804
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    Hysteretic spin crossover driven by anion conformational change

    N. Phukkaphan, D. L. Cruickshank, K. S. Murray, W. Phonsri, P. Harding and D. J. Harding, Chem. Commun., 2017, 53, 9801
    DOI: 10.1039/C7CC05998A

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