Jump to main content
Jump to site search

Issue 93, 2017
Previous Article Next Article

De-assembly of assembled Pt1Ag12 units: tailoring the photoluminescence of atomically precise nanoclusters

Author affiliations

Abstract

Considering the significant effect of the size of a nanocluster on its optical energy gap, we herein exploit the concept of de-assembly to render a blue-shift of the photoluminescent emission as well as an enhancement of the quantum yield (QY) of assembled M25 nanoclusters. The de-assembly splits an assembled M13-dimer Pt2Ag23(PPh)10Cl7 into a sole-M13-kernel Pt1Ag12(dppm)5(SPhMe2)2, via a Pt1Ag24(SPhMe2)18 nanocluster.

Graphical abstract: De-assembly of assembled Pt1Ag12 units: tailoring the photoluminescence of atomically precise nanoclusters

Back to tab navigation

Supplementary files

Publication details

The article was received on 02 Aug 2017, accepted on 30 Oct 2017 and first published on 30 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC05996E
Citation: Chem. Commun., 2017,53, 12564-12567
  •   Request permissions

    De-assembly of assembled Pt1Ag12 units: tailoring the photoluminescence of atomically precise nanoclusters

    X. Kang, L. Xiong, S. Wang, Y. Pei and M. Zhu, Chem. Commun., 2017, 53, 12564
    DOI: 10.1039/C7CC05996E

Search articles by author

Spotlight

Advertisements