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A new Pu(III) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

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Abstract

Crystals of a hydrated Pu(III) chloride, (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl3(H2O)5] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.

Graphical abstract: A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

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Publication details

The article was received on 02 Aug 2017, accepted on 12 Sep 2017 and first published on 12 Sep 2017


Article type: Communication
DOI: 10.1039/C7CC05988D
Citation: Chem. Commun., 2017, Advance Article
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    A new Pu(III) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

    R. G. Surbella, L. C. Ducati, K. L. Pellegrini, B. K. McNamara, J. Autschbach, J. M. Schwantes and C. L. Cahill, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC05988D

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