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Issue 76, 2017
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A novel polyoxometalate-based hybrid containing a 2D [CoMo8O26] structure as the anode for lithium-ion batteries

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Abstract

The proof-of-principle of an unusual fused γ-[Mo8O26]4− chain as an inorganic ligand is presented for the first time. By sharing two Mo–O edges, the γ-[Mo8O26]4− subunits are propagated into a one-dimensional (1D) zig-zag chain, which acts as a purely inorganic ligand binding octahedral Co(II) centers into a two-dimensional (2D) [CoMo8O26] sheet. This material exhibits high initial reversible specific capacity and stable reversible capacity when applied as an anode for lithium-ion batteries (LIBs).

Graphical abstract: A novel polyoxometalate-based hybrid containing a 2D [CoMo8O26]∞ structure as the anode for lithium-ion batteries

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Publication details

The article was received on 24 Jul 2017, accepted on 01 Sep 2017 and first published on 01 Sep 2017


Article type: Communication
DOI: 10.1039/C7CC05741E
Citation: Chem. Commun., 2017,53, 10560-10563
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    A novel polyoxometalate-based hybrid containing a 2D [CoMo8O26] structure as the anode for lithium-ion batteries

    X. Chen, Z. Wang, R. Zhang, L. Xu and D. Sun, Chem. Commun., 2017, 53, 10560
    DOI: 10.1039/C7CC05741E

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