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Consecutive reduction, radical-cyclization, and oxidative-dehydrogenation reaction of ortho-substituted diboryl compounds

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Abstract

An elegant synthetic route to a ladder-type di-borate compound 2a was reported based on the reduction, radical-cyclization, and oxidative-dehydrogenation reaction of 1. The existence of the biradical intermediate [1˙˙]2− was supported by both EPR measurements and DFT calculations.

Graphical abstract: Consecutive reduction, radical-cyclization, and oxidative-dehydrogenation reaction of ortho-substituted diboryl compounds

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Publication details

The article was received on 22 Jul 2017, accepted on 09 Aug 2017 and first published on 09 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC05689C
Citation: Chem. Commun., 2017, Advance Article
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    Consecutive reduction, radical-cyclization, and oxidative-dehydrogenation reaction of ortho-substituted diboryl compounds

    L. Yu, Y. Li, X. Wang, X. Wang, P. Zhou, S. Jiang and X. Pan, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC05689C

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