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The active site for the water oxidising anodic iridium oxide probed through in situ Raman spectroscopy

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Abstract

The structure of anodic iridium oxide (IrOx) under water oxidation was explored using in situ Raman spectroscopy and theoretical calculations. Isotopic substitution experiments and theoretical calculations confirmed formation of an Ir[double bond, length as m-dash]O species during oxygen evolution reaction.

Graphical abstract: The active site for the water oxidising anodic iridium oxide probed through in situ Raman spectroscopy

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Publication details

The article was received on 25 Aug 2017, accepted on 09 Oct 2017 and first published on 09 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC05669A
Citation: Chem. Commun., 2017, Advance Article
  • Open access: Creative Commons BY license
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    The active site for the water oxidising anodic iridium oxide probed through in situ Raman spectroscopy

    Z. Pavlovic, C. Ranjan, M. van Gastel and R. Schlögl, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC05669A

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